Msds browser format msds pdf download trichlorotrifluoroethane material safety data sheet navigation key 1. Firefighting measures suitable extinguishing media. May evolve toxic gases chlorides, phosgene, hydrocarbons, carbon oxides when heated to decomposition. Search results for phosgene solution at sigmaaldrich. Msds browser format trichlorotrifluoroethane material safety.
First aid measures ingestion never give anything by mouth to an unconscious person. There is little immediate irritant effect upon the respiratory tract, and the warning properties of the gas are therefore very slight. Tested to withstand exposure to acetone, dichloromethane, hydrofluoric acid, and other tough chemicals and solvents. Phosgene is a highly toxic gas with an osha immediately dangerous to life and health idlh limit of 2 ppm. As a dehydrating agent, phosgene can also lead to isocyanides, cyanides, and carbodiimides.
It is the responsibility of each person shipping, transporting or using phosgene to know and to comply with all applicable laws and regulations pertaining to shipping, labeling and placarding. Phosgene 75445 yes yes yes yes yes yes not regulated under california proposition 65. Your new online msds binder is a place for you to store the material safety data sheets you. Phosgene oxime is a manufactured chemical that was developed as a potential chemical warfare agent, but its use on the battlefield has never been documented. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. Safety data sheet according to regulation ghc gerling. Pdf phosgenation reactions with phosgene from triphosgene.
Fire and explosion evacuate area and contact emergency services. Pure phosgene oxime is a colorless, crystalline solid. Phosgene safety info thank you for your interest in the phosgene safety website of the international isocyanate institute. The information in the phosgene safe practice guidelines is intended to provide helpful ideas and guidance that users may wish to consider in a general sense. This document is only controlled while on the praxair, inc. Signs and symptoms of toxicity may be delayed for 24 hours. When transporting cylinders of compressed gas and cyrogenic liquids, safety should be the number one priority. Phosgenation reactions with phosgene from triphosgene. Our msds database is an easy to use, do it yourself tool, and best of all.
Phosgene is used in the manufacture of other chemicals such as dyestuffs, isocyanates, polycarbonates and acid chlorides. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or. Phosgene is the organic chemical compound with the formula cocl 2. Please ensure that this msds is received by the appropriate person.
Exposure to phosgene may cause irritation to the eyes, dry burning throat, vomiting, cough, foamy sputum, breathing difficulty, and chest pain. Hazardous combustion products may include carbon monoxide, carbon dioxide co2 phosgene, hydrogen chloride gas and chlorine gas. Phosgene is a valued industrial building block, especially for the production of urethanes and polycarbonate plastics. Phosgene carbonyl chloride cas 75445 ghs chemical container label. Feb 12, 2018 phosgene is a highly toxic substance that exists as a gas at room temperature.
Material is combustible and may form traces of hci, hf and traces of phosgene upon pyrolysis. The major pathological feature is delayed pulmonary edema. Finafloxacin hydrochloride safety data sheet section 2. Have the safety data sheet, and if available, the product container or label with you when calling a poison control center or doctor, or going for treatment. Cdc niosh pocket guide to chemical hazards phosgene. Protective equipment and precautions for firefighters as in any fire, wear selfcontained breathing apparatus pressuredemand, mshaniosh approved or equivalent and full. Stop the flow of gas or remove cylinder to outdoor location if this can be done without risk. Please log in if you want to browse through the more detailed information on this part of the site. Bistrichloromethylcarbonate btc,triphosgene is a versatile compound that enables highly efficient syntheses. It is not intended to be a howto manual, nor is it a prescriptive guide. Durable laminate that increases the label strength and resistance. Section 1 identification of chemical product and company. Details of the supplier of the safety data sheet manufacturer address makhteshim agan of north america, inc. Vandemark products are listed below by product categories.
Oxirane ethylene oxide safety data sheet ghs product identifier other means of identification 24hour telephone section 1. Page 4 of 11 pages halotron i sds part number 26930 methods for containment. The information provided in this safety data sheet is correct to the best of our knowledge, information and belief at the date of its publication. Dependable 3m adhesive vinyl that is built to resist harsh conditions. Phosgene safety phosgene is a common chemical intermediate utilized in the synthesis of numerous chemical intermediates used to produce pharmaceutical active ingredients, monomers for various polymers, pesticides, herbicides and other specialty chemicals.
The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. To view a pdf file of a technical data sheet tds or material safety data sheet msds, click on the corresponding download link. Phosgene is a gas at room temperature, but is sometimes stored as a liquid under pressure or refrigeration. Praxair cannot assure the integrity or accuracy of any version of this document after it has been downloaded or removed from our website. Disclaimer the sds samples above are collected from the internet by chemblink and. Phosgene is the organic chemical compound with the formula cocl2. Sds of phosgene, safety data sheets, cas 75445 chemblink. Chemical properties of phosgene cas 75445 download as pdf file download as excel file download as 2d mole file predict. As in any fire, wear selfcontained breathing apparatus pressuredemand niosh approved or.
Material safety data sheet educational innovations. Phosgene is an extremely versatile reagent allowing easy access to isocyanates, ureas, carbamates, carbonates, acyl and alkyl chlorides. Accidental release measures contain spill and collect, as appropriate. We want to help you prevent a disaster before it happens. Other companies are charging thousands of dollars to set up accounts and give you access to their msds online database. Links with this icon indicate that you are leaving the cdc website the centers for disease control and prevention cdc cannot attest to the accuracy of a nonfederal website. Chronic exposure to phosgene compounds may cause irreversible pulmonary. Owing to its poor water solubility, one of the hallmarks of phosgene toxicity is an unpredictable asymptomatic latent phase before the development of noncardiogenic pulmonary edema. Phosgene is a lung toxicant that causes damage to the capillaries, bronchioles and alveoli of the lungs, by decomposition to hydrochloric acid.